Very interesting discussion thread. Thank you, Andrew, for sharing the Villière et al. (2012) paper.
Martin, I hope you do investigate the effects of debourbage (preferably experimental-control design)...I will be very interested to hear the results. I haven't done any experiments with pre-fermentation debourbage myself, but I am very curious to know whether it makes a difference on the resulting flavors.
Howver, I did a little low-tech experiment with post-fermentation fining (more details) below and concluded that the batches without bentonite fining tasted better (albeit they were generally more cloudy) than those with bentonite fining. That was based on blind taste-testing on 10 people (my partner and I and my 8 guinea pig friends). So, I have put the bentonite on the shelf and don't have any plans to use it again.
If you want to know more details re: my experiment with post-fermentation fining...
1) I started with 5 different juices (all store-bought, pasteurized: 3 were organic and unfiltered; 2 were not organic and already cleared).
2) I pitched the same yeast in all 5 juices and did a side-by-side fermentation, attempting to treat all to the same conditions. FYI: I was aiming for a "stuck" fermentation to retain some residual sugars, so I did multiple rackings. [I did NOT use any sulfite. I treated the 3 unfiltered juices with pectinase the day before I pitched the yeast, but I did not add pectinase to the 2 clarified juices. I did, however, treat some of the juices with malic acid to get the pH down to 3.8.]
3) By Day 97, all fermentations were stuck, but some of the juices fermented more quickly than others and thus, the final O.G. ranged from 1.005 to 1.013. All 5 batches were still rather cloudy. [Not a surprise since the must had been pasteurized. Andrea Lea and Claude Jolicoeur helped answer my question about that a year of so ago when they explained that the pastuerization process may create a "heat set complex" that make the pectin haze permanent.]
4) I split each of the 5 batches in half and bottled 1/2 of each batch "as is" (despite its cloudiness). The other half of each batch I
treated with Bentonite slurry at the recommended dosage and sulfite (20 PPM for Batches #1-3 with pH~3.8 and 10 PPM for Batches #4-5 with pH~3.6).
5) Two weeks post-Bentonite, 2 of the 3 batches had cleared up fairly well; the other two batches not so much (one of which had been treated with pectinase pre-fermentation and the other had not been given pectinase but started out perfectly clear). I racked all of the batches off the sediment.
6) After letting it settle for another 3 weeks (Day 131), two of the batches were very clear (were initially unfiltered, but treated with pectinase pre-fermenation), another two were somewhat clear (one treated and the other not treated with pectinase), and the final batch was still very cloudy (originally clear juice that had NOT been treated with pectinase).
7) I bottled all of those batches on Day 131.
8) Six weeks after bottling the batches with Bentonite (2.5 mos after bottling batches without Bentonite), I did a blinded tasting with myself, my partner, and 8 of our guinea pig friends (none of us are true cider connoisseurs, but we have opinions about what we like and don't like).
Conclusions from the blinded tasting:
1) I am not going to bother with Bentonite in the future. While Bentonite did yield better clarity for some juices, there was very little evidence that it improved flavor. In fact, in most cases, it appeared to be detrimental to the flavor. For the two juices that scored the best in the tasting, the majority of raters preferred the non-Bentonited version (Whole Food 365: the non-Bentonite version won by a landslide: 9 to 1; Safeway O Organics: the non-Bentonite version won 5 to 4, with one person who could not distinguish a difference). The only juice in which the Bentonite version won was the juice that scored the worst in our tasting (Oliver’s Market organic juice made from local apples: bentonite version won 6 to 2, with 2 people who were unable to distinguish a difference).
2) If I am using a pasteurized, store-bought juice, I will only use Whole Foods 365 or O Organics juice from now on. [Kirklands, Trader Joe’s and Oliver’s were clear losers.]
3) Like Chris and I, our friends also like residual sugars (the final scores were directly related to the amount of residual sugar in the finished cider).
4) Next time, I will include a truly “dry” cider in the tasting so the raters know what “dry” really tastes like. Even I was too hard on the “losers”. I gave the worst one a score of 2. Yet, I have made many batches of cider that are far worse than that, and I have tasted a lot of commercial ciders that were also way worse. A local commercial cider that tasted (to me) like shoe polish comes to mind…
Winners and Losers
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The overall winner (with a mean score of 8.2 out of 10) was Whole Foods 365 Organic juice without bentonite. This was the sweetest cider (FG=1.013 at the time of bottling, which puts it in the “medium-sweet” category by BJCP guidelines) with ABV 5.2%. Comments included: Yum! Light body, floral, bright notes, slightly sweet & smooth, light body, not much smell.
The runner up (with a mean score of 7.3) was Safeway’s O Organics juice without bentonite. It was not quite as sweet (FG=1.009 at bottling, putting it at the top of the “medium” category) with ABV 5.5%. Comments included: Full-bodied, smokey, more apple flavor than the version with bentonite, good carbonation, nice aroma, good sweetness, some character, balanced, acidic aftertaste, tart, sharp complex, slightly sulphury, good carbonation.
Third and fourth place went to O Organic with bentonite (mean=7.0). It had better clarity than the version without bentonite, but a strange after flavor. To me (and several others), it had clear diacytl (butterscotch) aroma/flavor (which I liked, even though I know it is considered a defect). One person noted that is tasted almost like a moscato.
Fourth place went to Whole Foods with bentonite (mean=6.7), respectively. One person thought it had caramelly notes (said thought it was "darker than the version without bentonite"). A bit bitter. One person thought it tasted more like wine (higher alcohol) than the version without bentonite.
Trader Joe's took 5th & 6th place. People noted off aromas, high acidity, thin, watery.
Kirland (Costco) took 7th and 8th place. Some thought it bitter (one person said, “tastes like ear wax"). Odd smell, very sharp, odd aftertaste, tasteless.
Oliver’s Organic juice took last place (9th place at mean=4.4 for the version with bentonite, 10th place at mean=4.3 for the version without bentonite). Lacked flavor (or odd flavor), odd after-taste. Almost everyone said it was “dry” (FG=1.005 at the time of bottling, which would put it in lower end of the “medium” category with ABV 7.0%, but I think it probably bottle conditioned and fermented out at least some of that sugar…nonetheless I suspect it is still very far from “dry”).
Cheers,
Dana Glei
Budding Cider Maker in Sonoma County, CA
(and social demographer who enjoys the opportunity to play around with experimental-control research design, which I don't get to do my day job)