Yes, one can export animation frames from VPython. In the Contributed section at
vpython.org is a module originated by Ruth Chabay which lets you output the current 3D objects as a text file in Pov-ray format. Pov-ray is a free ray-tracer that generates higher-quality images than is possible with the real-time rendering of VPython.
However, by far the easiest way to generate a movie, albeit with the lower quality of the real-time rendering, is to use a video capture program such as Camtasia. I think there are a lot of such programs.
Bruce