@Anand, its my daily bread :P
Just to add on to my explanation , lets say you have dataset 3
Candidate | Email Id
Darria | Darria123 at gmail . com
Anand | Anand456 at yahoo . com
The analysis you want to perform , requires you to find the email provider (gmail , yahoo etc) of the candidate . This is not straight away possible on the email field , but since you know the general format of an email id ( something @ something . something ) . YOu can do basic string operation on email field to find the email provider. So this makes "email id", in this dataset a semi structured data field.
Examples of structured files : files where data is in rows/columns format
Examples of unstructured files : log (text) files, audio/video files
Examples of unstructured data : xml files, email ids etc