I don't know why the differences in versions, but If I were
troubleshooting I would try these things first:
1. Does the same thing happen in chromium-based browser ? If yes,
that might mean server configuration issue or a trust issue.
2. Where did the certificate come from? Is it self-issued, do you
have your own CA, did you get it from somewhere else?
2a. Press "Mostra el certificat"/"View Certificate" and see who the
certificate is issued by
2b. Does that CA show in Tools -> Privacy & Security ->
Security -> View Certificates -> Authorities
3. Looking at the Apache server, - Are you using Mozilla's
recommended settings:
https://ssl-config.mozilla.org/ (Apache ->
Intermediate). Thinking mostly about SSLProtocol &
SSLCipherSuite settings.