Hello Dan,
Whether you decide to calibrate the steps per mm in the firmware or the flow percentage (or material multiplier in your case) in the slicer is up to your preference and the result will be the same.
To calibrate we print a simple object like a cube in vase mode so there is a single shell.
We ignore the first layers as these can be affected by bed adhesion, warping and bed leveling.
We only need a few layers in height printed, about at least 10 or so. We measure the actual layer width printed and compare it to the layer width asked in the slicer.
With those values we can calculate the ratio of layer width printed vs asked.
Example: We set the layer width to 4.5mm in the slicer and we actually obtained 5mm, 4.5/5=0.9.
With this ratio we can determine the new steps per mm or flow % to set.
Example: The steps per mm were 800 so the new updated steps are 720.
Alternatively we can keep the steps at 800 and change the flow percentage in the slicer instead, in the same example if the slicer percentage was at 100%, the new value is 100*0.9=90%.
Example 2: Asked layer width: 4.5mm, Actual layer width: 4.2mm, Steps per mm: 720, Flow %: 90%.
Ratio to update values with: 4.5/4.2=1.071
New steps per mm: 720*1.071=771.12 or new flow %: 96.39%
We repeat this process as much as needed until we obtain a satisfying result for our purposes and how tight tolerances need to be for our project.
In your case it is a multiplier to 1 and not a percentage so for example 96.39% would be a 0.9639 multiplier.
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