[+alexmos]
Can you clarify what your goal is? If it's to disable full Site Isolation and instead isolate only sites that users log into (as we do on Android), I'm not sure how easy that is due to the need for the component updater to get the list of sites. You can use chrome://flags/#site-isolation-trial-opt-out on non-enterprise-enrolled builds to turn off full Site Isolation, and I'll let Alex say whether there's a way to simulate the Android "list of sites" behavior on other platforms.
In contrast, "Default process" isn't enabled for any platform, but can be experimented with by enabling the ProcessSharingWithStrictSiteInstances feature. It causes Chrome to create strict SiteInstances for every site, but allows them to share a process (using OOPIF codepaths even though the frames are in the same process). It's orthogonal to which sites require dedicated processes, which is controlled by the Site Isolation setting described above. We don't plan to proceed with this mode directly; the next steps for that are introducing a FrameGroup abstraction, as outlined here:
Hope that helps,
Charlie