There are some things you might want to copy, some things you might
not want to copy, it's complicated. But, realistically, for a kiosk
setup, it probably doesn't matter, you probably just want to set it up
as you want it, quit completely, then use that as your canonical
version.
Not sure where you're going with using cron and sleep and stuff. Just
write a launcher script something like:
cat >chromium_launcher <<EOF
#!/bin/sh
rsync -a /path/to/canonical/Default/../ /path/to/real/
exec /path/to/chromium --user-data-dir=/path/to/real/
EOF
chmod +X chromium_launcher
Then launch chromium_launcher instead of chromium. That way the data
is always copied beforehand. Or put it all in a loop so that it
restarts fresh every time things crash or exit.
-scott