As you probably know by now, ffvp9 outperforms libvpx-vp9 (which is currently used by Chrome) especially because it has good multi-thread support. (libvpx-vp9 has it as well, though it's still slower) [1][2]
libvpx-vp9 performing poorly is an issue because, for users, it means that Videos in Chrome stutter (ie drop frames), while it works perfectly fine in other browsers/players. This is especially the case for resolutions beyond FullHD.
YouTube converting more and more videos from codecs that have very mature decoders (AVC) to VP9 doesn't help with that either (though, to be fair, less buffering is probably a higher priority than some framedrops)
I don't have metrics regarding how many users are affected by this, but since I see at least one thread per week in the help forums, I'd say "quite a few".
In a discussion almost a year ago, Dale Curtis stated that at at that time, there are no plans to switch. [3]
Since then, ffvp9 has improved; VP9 profiles other than 0 are supported and 32bit is optimized as well [4]. Meanwhile, libvpx did get multi-threading, but it doesn't work in Chrome and is actually slower than it is without [5]
The question is: Should libvpx-vp9 get ditched in favor of ffvp9?
The "I-only-watch-YouTube-on-desktop"-me says "definitely yes, asap". The "I-can't-code"-me says "maybe the devs have something to object, better ask them" :)