free continuum states- are these ever included?

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mike marchywka

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Nov 14, 2025, 6:49:35 PM (8 days ago) Nov 14
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Looking at some earlier work on hydrogen the authors suggest the free unbound
continuum states are important to getting the right answer.  Are these ever
considered in current codes ? All I've seen is number of states and maybe something
about the vacuum level. IIRC in the equation-of-motion codes the continuum was
a problem.  Does this contribution go away in larger molecules or infinite periodic
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