Ionization energy, work function and absurdity of modern science
sorin
The neglected ionization energy variation for isoelectronic series can
reveal more useful information about electrons structure; the problem
is these data are in contradiction with actual quantum theory.
The quantum prediction for work functions values are in contradiction
with experiments; for metals, ionization energy and work function must
be equal but in reality they are not.
For other classes of compounds quantum mechanic fails again to predict
something. A striking example is the case of metallic oxides having
work functions values smaller then metals. It is outrageous how a
covalent or ionic bound liberate electrons easier then a metallic
bound in frame of actual physics.
The improved link:
http://www.elkadot.com/chemistry/Ionization%20energy%20and%20work%20function.htm
Regards
Sorin Cosofret
Autymn D. C.
>The neglected ionization energy variation for isoelectronic series can
>reveal more useful information about electrons structure; the problem is
>these data are in contradiction with actual quantum theory.
>The quantum prediction for work functions values are in contradiction
>with experiments; for metals, ionization energy and work function must be
>equal but in reality they are not.
That is your prediction, shit-head cretin liar, not QM's. Work
function on room-temperature solid elements is smaller than the atomic
state due to a shallower charge weall.
>For other classes of compounds quantum mechanic fails again to predict
>something. A striking example is the case of metallic oxides
>having work functions values smaller then metals. It is outrageous
>how a covalent or ionic bound liberate electrons easier then a metallic >bound in frame of actual physics.
bond, retard
It does not and is not, nor did you ever use quantum mekanics to
predict anything. This is elèctrokemics and elementary maths, which
you fail again. Thorium has four valent charges, whereas thoria has
16 from the oxygen atoms; therefore whatever enthalpy the latter
contribute is overwhelmed by the extra charges. Work function is a
specific enthalpy rather than molar.
-Aut