In alt.home.repair, on Wed, 18 Jan 2023 09:05:29 +0530, mike
IIRC when cars had metal bumpers and people didn't have such good jumper
cables, they would touch the bumpers together in place of the negative
cable. And then maybe it could leave damage on the chrome from
sparking. ??? Now all the bumpers are covered in plastic or rubber and
it makes no difference. But the warning is still there.
>
>Then they said positive first.
>Why?
>
>Once started, they say remove the negative cable first.
>Why?
The second goes with the first, so that making/breaking is with the
negative cable, but that leaves the origial question. The correct
answer seems counter-intuitive. I used to know the answer and it's not
obvious. It had to do with accidentally ....aha it had to do with
accidentally touching both cables to the frame of the car. Say you've
hooked it up to the car with the good battery, and then you connect the
negative first. Then while you're trying to connect the positive (and
sometimes that's not easy. It has a cover or it's tucked away, or you
can see it but can't get the clamp on, you touch the metal body or
engine or frame of the car. Now you have both cables touching the frame
while at the other end, at the car you are using to jump your own, they
are connected to a good battery. Big spark. Thing you are touching it
to gets damaged. If you manage to clamp or hold it on, cables get hot,
insulation melts.
If you connect the positive first, you know you have that cable in the
right place, and then the ground cable would have to accidentally touch
specifically the positive terminal to be a short circuit. Anything else
it touches would be okay. In fact they also urge people to connect not
the negative battery post but to some other body or frame part, so that
that spark is away from the battery where the hydrogen is generated.
I suppopse hydrogen must have been a problem at least one time in
history -- a spark will ignite the hydrogen, and the flame could spread,
I suppose, to the hydrogen still in the battery, which would cause the
battery to explode and burst which will ruin the battey and spray acid
all over the place. But as Rod said, hydrogen is light and disperses
quickly and iirc it's only made when the battery is charging (wrong. See
below) and is also (so this is wrong too:) discharged enough to take a
charge, and your dead battery lately, unless it has been and ylu got
interrupted and have to put the cables back on. And the good car
battery has enough alternator voltage to charge all the time, but it's
probably fully charged and not making any hydrogen anyhow.
So to correct myself, it makes hydrogen when the battery is discharging.
I suppose by the time you go find someone to jump the car, there has
been loads of time for the hydrogen to blow away. Maybe the explosion
happened in a testing lab where they were all set up and they discharged
the battery and then recharged it immediately. ?????
So this is less likely to be a problem and I still use my negative
battery post for a jump, but the first question, negative on last, makes
sense. Even though I know where to put the cable, eventually I will
touch something I shoudln't so it's better to go in that order.
Very rarely, unless the charging voltage of the alternator is too high,
because the regulator isn't working right. These things continue to get
more reliable.
>This says to add water after every ten charging cycles?
>Isn't that like every ten days?
Or ten trips??
I don't know what they mean by charging cycle, but I check maybe once a
year. If I needed more than a little bit of water, I'd would plan to
check again in a month or two. Doesn't mean I would do so. I've been
sluggish and actually checked only once in the last 5 years. Two years
ago. I did need quite a bit of water.
>And how do you know how much to add?
When the water looks flat, it needs water. When the water reaches the
right level, it touches the bottom of the tube-like thing that is the
filler for the chamber and you can see the meniscu, where the water
curls up at the edges, so when you look, it's not flat everywhere. It's
curled at the edges like water in a glass is where it touches the glass.
That means you've put in enough water.
https://en.wikipedia.org/wiki/Meniscus_(liquid) Water forms a concave
meniscus. Maybe liquid mercury forms a convex one. Oh, yeah sure
enough, that's what it says. You can see it in any glass of water,
although I think soap keeps it from forming.
>They say add water to the "splash plate" but what is that?
Never heard that term but they must mean what I just said.
>
>They say the six chambers produce 2.1 volts each for 12.6 volts?
>Isn't it more than that?
No. Charging voltage is intended to be 13.4 or something like that
because if you only have 12.7 it will charge too slowly to recharge what
it lost during starting or running lights while the engine is off.
>
>They say adding water before charging will make it overflow.
>Does it really change the water level that much from dead to charged?
I'm sure they didbn't make this up, but I don't worry about timing like
that and I've never noticed it overflow. OTOH, I have had shmutz on the
top of the battery, white crud, and that is from the acid in the
battery. Plus even if you don't see white crud, if you pour some baking
powder on the battery and then add water (this is to the outside so it
doesn't have to be distilled) and you see bubbles, that means there is
acid on top of the battery. When the bubbling ends, all the acid has
been neutralized. There very often is some. (Even sealed batteries have
a vent iirc, but maybe not). does it get there because of evaporation
and then condensing, can acid do that? or did the battery overflow when
I was driving. I very rarely overfilled even one of the six chambers,
and even then there is room for expansion. You have to overfill a lot
before it's near the top. .
>And what happens if you tap water instead of distilled?
Tap water has minerals and they would combine with the sulfuric acid
without generating electricity, or maybe with the lead itself. Something
like that. They'd get involved in the chemical reactions and slightly
lessen the power of the battery. Pb + H2S04 -> PbS04 + H2, when
discharging**, and the reverse when charging, or something like that.
The reverse is tricky because the PbS04 should release the lead and it
should go back onto the plates. If you charge too fast it does but it
gets covered by some other compound, probably PbS04, and it makes
"spongy lead". then the surface of the plates isn't entirely lead and
the battery isn't as powerful as it originally was. Also some lead etc.
drops into the bottom, which is empty for a half inch or an inch, so
the junk in the bottom doesn't short out the plates. Not easy to
build a good car.
**Oops This would mean that hydrogen is made during discharging, not
charging like I said.
As to sealed batteries, even non-sealed batteries pretend to be sealed
now. They don't have 6 screw on caps. They have 2 wide flat plastic
plates you can pry off, that look similar to sealed batteries. IIRC
they hoped car charging systems would all work so well that sealed
batteries would be fine, but it didn't always work out that way and
people still had to add water and they were annoyed when they coudln't,
so non-sealed made a resurgence, but they try to look like sealed so the
police and border guards won't stop and interrogate them.