i believe plexi is preferred to polycarbonate for windows unless you
need the extra shatter resistance of polycarbonate. polycarbonate is
more prone to scratching, has lesser clarity and without UV protection
will yellow
on either one if you want to use a saw, you'll want a special plastic
blade; regular saw blades will cause a lot of chipping and will likely
melt the plastic, creating a goo that is bad news for both the plastic
and the saw. you'll still probably need to clean up the edge
afterwards with a file / sharp blade though.
don't know much about UV resistant polycarbonate, except that you can
apply a sheeting over it to protect it from UV... though i imagine
that unless professionally installed you'll lose a fair amount of the
optical quality.