As far as I know, what you are asking is not physically possible.
A PHY has a modulation capability hardcoded (a chip that does the modulation), so it does not make sense to me to "dynamically " change the modulation.
You could, however, have 2 interfaces in a single node. In this way, you could install one interface with 1 modulation and the 2nd interface with a different modulation scheme.
Then you could switch between the used interfaces dynamically during the simulation.
Regards,
Al