We're in the process of doing some. You can find current results here.
http://www.mongodb.org/display/DOCS/Performance+Testing
The "problem" is that MongoDB is so fast, performance tends to be
limited by driver performance :)
The main differences between MongoDB and CouchDB are speed and query
model.
1) MongoDB is very, very fast. We can do inserts north of 20k/sec,
where on CouchDB on the same hardware, about 250-300/sec is the max.
2) The query models are quite different - MongoDB has a query model
that is direct, uses indexes, and very similar to the model you might
be used to in an RDBMS (doesn't use SQL though). CouchDB uses a
"view" system which, while very nice, doesn't allow arbitrary queries,
and limits to what you can express in a key/value lookup.
Also, MongoDB's storage format - while akin to JSON - goes beyond JSON
by adding a few types like date, which is important for querying...
I guess just as important a question... what problem are you trying to
solve? What do you plan on using the DB for?
geir