A strain of cockroaches in Europe has evolved to outsmart the sugar traps used to eradicate them.
American scientists found that the mutant cockroaches had a "reorganised" sense of taste, making them perceive the glucose used to coat poisoned bait not as sweet but rather as bitter.
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As far as witnessing that process is concerned, the closest thing I've ever read about concerns populations of squirrels on adjacient islands in the Philippines. On one island, male squirrels can breed with females on both of two adjacent islands. But in the other population, interbreeding always produces infertile off-spring. Are they sepearate species? Well, this discovery has stressed our very definitions! There is an active flow of genetic information in only one direction; in the other direction it's cut-off. This is now recognized as an intermediary step in the creation of a new species. After all, it has to happen at some point, and in the case of these squirrel populations, we've caught the process at mid-step. Evidently a rather short-lived half-step, which shows how this process takes place; snipping the connection one side at a time.
Our definitions of species is being stressed. Firtle offspring is not a requirement any longer. If the offspring are Ill suited to survive, or will not come into being in nature, then sepearate spices exist. For example, the liger and tigon are both firtle, but lions and tigers are reguarded as sepearate species. Also, there are dolphin/whale hybrids that are furtle, but they don't exist in nature, so they are also reguarded as separate species. There are butterfly's that can breed with subspecies on the other side of mountain ranges... But the offspring can't fly, so they are doomed. That's sufficient in the newer definitions of what it means to be a species, but, ironically perhaps, our definitions themselves are continuing to 'evolve'.
On a side note, the mixture model you suggested has been used before. it was used to defend the notion that cigarets don't cause cancer. Rather, being cancer prone makes one tend to enjoy cigarets. You see, people are of two types, a single population is actually a mixture. In one sub-population, we have cancer prone cigarette fans and in the other we presume the existence of another sub-population of less cancer prone people that tend to not enjoy cigarets. A convenient mixture model like the one you suggest is contrived, essentially reverse engineered specifically to argue that the researchers are foolish, and have been misled, and thus no signs of evolution are taking place, and cigarets are actually healthy to use... I'm not sure why you're motivated to fabricate a contrived explanation like this, but to each his own.