Per our recent announcements and our documentation, you are advised to
use datacenter-specific URLs:
http://groups.google.com/group/mailchimp-api-announce/browse_thread/thread/30827b746cc138f0
http://www.mailchimp.com/api/rtfm/
The current IPs for all hosts that could be contacted are:
api.mailchimp.com
69.20.10.80, 69.20.10.85, 74.205.3.112
us1.api.mailchimp.com
69.20.34.200, 207.97.212.229, 69.20.22.194
us2.api.mailchimp.com
74.63.51.85
We currently use round-robin DNS load balancing for those, so you
could hit any of them depending on the endpoint URL you are using. We
strongly recommend not hard-coding these whenever possible since they
can (and will) change without notice. I suppose if you must, though,
then you must - you may, however, want to use the /24 for each to have
a better chance of already having new addresses white-listed.
jesse