Hey, I used to work at Tiranti, yes expensive but its a shop
Casting any type of silicone into silicone is difficult, not impossible but you need a lot of release agent, if you screw up you mould will be ruined.
PU is better, although watch out some polyurethanes can be inhibited by the type of silicone you use. ( I cant quite remember but it was something like tin cure is bad, just read the label on the bottle or leaflet)
If you can, the best moulds are rigid fibreglass or PU as contrasting rigid against flexible is easier to mould