Images in the description balloon are currently cached and only refreshed on startup. Alternately you can specify your webcam url as the placemark's icon:
<Placemark>
<description><!CDATA[<img src="
http://www.vid.nl/ImageCamera/cam_5.jpg">]]></description>
<name>Test Placemark</name>
<LookAt id="khLookAt1521">
<longitude>5.450150615910606</longitude>
<latitude>52.37543080603724</latitude>
<range>134230.0014479083</range>
<tilt>4.185474337102344e-011</tilt>
<heading>-0.0001420648917350513</heading>
</LookAt>
<styleUrl>root://styleMaps#default+nicon=0x307+hicon=0x317</styleUrl>
<Style id="khStyle1522">
<IconStyle id="khIconStyle1526">
<Icon>