Nature Reports Climate Change
Published online: 20 November 2008 | doi:10.1038/climate.2008.122
Carbon dioxide emissions and their associated warming could linger for millennia, according to some climate scientists. Mason Inman looks at why the fallout from burning fossil fuels could last far longer than expected.
Distant future: our continued use of fossil fuels could leave a CO2legacy that lasts millennia, says climatologist David Archer
123RF.COM/PAUL MOORE
After our fossil fuel blow-out, how long will the CO2 hangover last? And what about the global fever that comes along with it? These sound like simple questions, but the answers are complex — and not well understood or appreciated outside a small group of climate scientists. Popular books on climate change — even those written by scientists — if they mention the lifetime of CO2 at all, typically say it lasts "a century or more"1 or "more than a hundred years".
"That's complete nonsense," says Ken Caldeira of the Carnegie Institution for Science in Stanford, California. It doesn't help that the summaries in the Intergovernmental Panel on Climate Change (IPCC) reports have confused the issue, allege Caldeira and colleagues in an upcoming paper in Annual Reviews of Earth and Planetary Sciences2. Now he and a few other climate scientists are trying to spread the word that human-generated CO2, and the warming it brings, will linger far into the future — unless we take heroic measures to pull the gas out of the air.
University of Chicago oceanographer David Archer, who led the study with Caldeira and others, is credited with doing more than anyone to show how long CO2 from fossil fuels will last in the atmosphere. As he puts it in his new book The Long Thaw, "The lifetime of fossil fuel CO2 in the atmosphere is a few centuries, plus 25 percent that lasts essentially forever. The next time you fill your tank, reflect upon this"3.
"The climatic impacts of releasing fossil fuel CO2 to the atmosphere will last longer than Stonehenge," Archer writes. "Longer than time capsules, longer than nuclear waste, far longer than the age of human civilization so far."
The effects of carbon dioxide on the atmosphere drop off so slowly that unless we kick our "fossil fuel addiction", to use George W. Bush's phrase, we could force Earth out of its regular pattern of freezes and thaws that has lasted for more than a million years. "If the entire coal reserves were used," Archer writes, "then glaciation could be delayed for half a million years."
"The longevity of CO2 in the atmosphere is probably the least well understood part of the global warming issue," says paleoclimatologist Peter Fawcett of the University of New Mexico. "And it's not because it isn't well documented in the IPCC report. It is, but it is buried under a lot of other material."
It doesn't help, though, that past reports from the UN panel of climate experts have made misleading statements about the lifetime of CO2, argue Archer, Caldeira and colleagues. The first assessment report, in 1990, said that CO2's lifetime is 50 to 200 years. The reports in 1995 and 2001 revised this down to 5 to 200 years. Because the oceans suck up huge amounts of the gas each year, the average CO2 molecule does spend about 5 years in the atmosphere. But the oceans also release much of that CO2 back to the air, such that man-made emissions keep the atmosphere's CO2 levels elevated for millennia. Even as CO2 levels drop, temperatures take longer to fall, according to recent studies.
"The climatic impacts of releasing fossil fuel CO2 to the atmosphere will last longer than Stonehenge, longer than time capsules, longer than nuclear waste, far longer than the age of human civilization so far."
David Archer
Earlier reports from the panel did include caveats such as "No single lifetime can be defined for CO2 because of the different rates of uptake by different removal processes." The IPCC's latest assessment, however, avoids the problems of earlier reports by including similar caveats while simply refusing to give a numeric estimate of the lifetime for carbon dioxide. Contributing author Richard Betts of the UK Met Office Hadley Centre says the panel made this change in recognition of the fact that "the lifetime estimates cited in previous reports had been potentially misleading, or at least open to misinterpretation."
Instead of pinning an absolute value on the atmospheric lifetime of CO2, the 2007 report describes its gradual dissipation over time, saying, "About 50% of a CO2 increase will be removed from the atmosphere within 30 years, and a further 30% will be removed within a few centuries. The remaining 20% may stay in the atmosphere for many thousands of years." But if cumulative emissions are high, the portion remaining in the atmosphere could be higher than this, models suggest. Overall, Caldeira argues, "the whole issue of our long-term commitment to climate change has not really ever been adequately addressed by the IPCC."
The lasting effects of CO2 also have big implications for energy policies, argues James Hansen, director of NASA's Goddard Institute of Space Studies. "Because of this long CO2 lifetime, we cannot solve the climate problem by slowing down emissions by 20% or 50% or even 80%. It does not matter much whether the CO2 is emitted this year, next year, or several years from now," he wrote in a letter this August. "Instead ... we must identify a portion of the fossil fuels that will be left in the ground, or captured upon emission and put back into the ground."
Unlike other human-generated greenhouse gases, CO2 gets taken up by a variety of different processes, some fast and some slow. This is what makes it so hard to pin a single number, or even a range, on CO2's lifetime. The majority of the CO2 we emit will be soaked up by the ocean over a few hundred years, first being absorbed into the surface waters, and eventually into deeper waters, according to a long-term climate model run by Archer. Though the ocean is vast, the surface waters can absorb only so much CO2, and currents have to bring up fresh water from the deep before the ocean can swallow more. Then, on a much longer timescale of several thousand years, most of the remaining CO2 gets taken up as the gas dissolves into the ocean and reacts with chalk in ocean sediments. But this process would never soak up enough CO2 to return atmospheric levels to what they were before industrialization, shows oceanographer Toby Tyrrell of the UK's National Oceanography Centre, Southampton, in a recent paper4.
Finally, the slowest process of all is rock weathering, during which atmospheric CO2 reacts with water to form a weak acid that dissolves rocks. It's thought that this creates minerals such as magnesium carbonate that lock away the greenhouse gas. But according to simulations by Archer and others, it would take hundreds of thousands of years for these processes to bring CO2 levels back to pre-industrial values (Fig. 1).
Model simulation of atmospheric CO2 concentration for 40,000 years following after a large CO2 release from combustion of fossil fuels. Different fractions of the released gas recover on different timescales. Reproduced from The Long Thaw3.
Several long-term climate models, though their details differ, all agree that anthropogenic CO2 takes an enormously long time to dissipate. If all recoverable fossil fuels were burnt up using today's technologies, after 1,000 years the air would still hold around a third to a half of the CO2 emissions. "For practical purposes, 500 to 1000 years is 'forever,'" as Hansen and colleagues put it. In this time, civilizations can rise and fall, and the Greenland and West Antarctic ice sheets could melt substantially, raising sea levels enough to transform the face of the planet.
The warming from our CO2 emissions would last effectively forever, too. A recent study by Caldeira and Damon Matthews of Concordia University in Montreal found that regardless of how much fossil fuel we burn, once we stop, within a few decades the planet will settle at a new, higher temperature5. As Caldeira explains, "It just increases for a few decades and then stays there" for at least 500 years — the length of time they ran their model. "That was not at all the result I was expecting," he says.
But this was not some peculiarity of their model, as the same behaviour shows up in an extremely simplified model of the climate6 — the only difference between the models being the final temperature of the planet. Archer and Victor Brovkin of the Potsdam Institute for Climate Impact Research in Germany found much the same result from much longer-term simulations6. Their model shows that whether we emit a lot or a little bit of CO2, temperatures will quickly rise and plateau, dropping by only about 1 °C over 12,000 years.
"The longevity of CO2 in the atmosphere is probably the least well understood part of the global warming issue."
Peter Fawcett
Because of changes in the Earth's orbit, ice sheets might start to grow from the poles in a few thousand years — but there's a good chance our greenhouse gas emissions already may prevent that, Archer argues. Even with the amount of CO2 emitted so far, another ice age will almost certainly start in about 50,000 years. But if we burn all remaining fossil fuels, it could be more than half a million years before the Earth has another ice age, Archer says.
The long-term effects of our emissions might seem far removed. But as Tyrrell says, "It is a little bit scary, if you think about all the concerns we have about radioactive wastes produced by nuclear power. The potential impacts from emitting CO2 to the atmosphere are even longer than that." But there's still hope for avoiding these long-term effects if technologies that are now on the drawing board can be scaled up affordably. "If civilization was able to develop ways of scrubbing CO2 out of the atmosphere," Tyrrell says, "it's possible you could reverse this CO2 hangover."
Mason Inman is a freelance science writer currently based in Pakistan.
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I would like to know more about the CROPS program if you have a reference
But a propos "when the trees die", they don't die under commercial
forrestation but get cut down when growth slows and the rate of increase of
value falls below the operator's cost of borrowing. When that happens, if
there is co-produced fuel and timber, is that some fossil fuel gets left in
the ground and some other timber elsewhere gets left standing (hopefully in
natural biodiverse forest), an ongoing process for "chipping away at
atmospheric CO2 yearly" that can also support both REDD and biodiversity
objectives.
In a 'normal' commercial plantation there are equal area stands of all ages
of maturity from just planted to due to be felled next year. Annual growth
shifts each stand one year towards maturity, so that the average age of
stand is half the maturity age and there is a total standing stock of carbon
equal to approximately half of the maximum possible if all the stands were
left unfelled after growing to maturity and then left to die (which would
yield a zero return on investment).
While a new forest is growing towards the maturity of its first stand, and a
new stand is planted each year so as to eventually result in a normal
forest, the "chipping away" comes from annual average growth of the forest,
which ceases when the first stand is felled since thereafter annual felling
removes as much C as is captured by the annual growth of the rest of the
forest.
Increased "chipping away" results from routing the fuel fraction through one
of the negative emissions systems, biochar or BECCS, which results in C
being stored as nearly pure C in the soil or as CO2 deep underground, as
well as in leaving fossil fuel underground.
Decreased chipping away results if the trees left standing in natural
forests die off. A forthcoming paper by Len Ornstein suggests (from
memory - some time since I saw the draft) that about 1Gt of carbon annually
could be kept from the atmosphere if an organised program existed for
sequestering C that would otherwise be returned to atmosphere following
natural treefall.
Peter
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To: <pre...@attglobal.net>; <agas...@nc.rr.com>; <kcal...@stanford.edu>;
<geoengi...@googlegroups.com>
Sent: Sunday, May 17, 2009 4:20 AM
Subject: Re: [geo] Re: [clim] Fwd: White/Cool Roofs Memo to MEF (Major
Economies Forum)
Peter:
I might point out that commercial reforrestation works hand in hand
with deep ocean sequestration as well. Forest growth can hold CO2 for
centuries, but when the trees die, much of their debris can be
sequestered in deep water, a la the CROPS program. Chipping away at the
CO2 yearly makes sense, and each seasonal year we neglect doing it,
that CO2 will be with us a long time: Sequestration by installment.
Gregory Benford
.
.
.
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Climate Change Video:White Paint A Weapon Against Climate Change? CBS 13 /
CW 31 Sacramento
Caif. TV reporter on top of the roof of the TV station discusses the
advantages of white roofs in reflecting sunlight. Notes that white roofs
for commercial buildings are required in Calif. A more balanced and
accurate report than from the CBS Early Show that I renamed the Morning
Show. Morning, Good Morning, Early, Today, it's all the same. One person
commented that I shouldn't be watching this crap, but bad as it is, millions
of people do and their opinions are largely formed by what they see and hear
on these general interest programs, moreso now with the demise of print
newspapers. The local TV news briefly mentioned Chu's statement on this, so
it has been fairly widely disseminated, although I don't think the public or
the media actually understands the potential limits to it or the time scales
and effort involved.
I've also attached some pictures I shot in early April of the roof of a
local Sam's Club warehouse building in Durham, NC (501, 502, 503) to
illustrate some of the problems with white roofs, namely that while they
start out white, they don't stay that way. This particular building is part
of a large shopping center that sits on the site of the former South Square
Mall for those of you familiar with the area. A Target and some other
stores make up the rest of the structure which is nearly a quarter of a mile
from one end to the other. It's about 5-years old and I estimate the total
roof area to be around 300,000 SF.
When the building was new, the roof was quite white and shiny, much like
virgin white polyethylene sheeting (see my Roomba videos at weatherman2050
on YouTube for comparison shots of new and used white plastic.) Today,
however, the roof is a dingy light gray in color which seems to revert back
to white again when it rains or of course, snows. I don't think management
makes any effort to clean the roof, relying on the wind and rain to do the
job. To be fair about this, I've seen the roofs of other commercial
buildings in this area that do appear white, but without knowing their age
or when the roof was installed which may be different, it is difficult to
tell the history.
Also shown are shots of the nearby sidewalk where the pictures of the roof
were taken. The roof is now about the same whiteness as the concrete
sidewalk (505), but brighter than the adjacent asphalt (506). According to
the Akbari/Rosenfeld plan, as I understand it, degradation of the roof
albedo to around 0.6 total solar is factored into the estimates for the
lifetime of the roof amd associated reduced CO2eq forcing and washing is not
a requirement. Correct me on this if I'm wrong guys. The Sam's Club roof
is still probably within the 0.6-0.8 range, although without measurements,
it is impossible to know for certain.
Most commercial buildings have flat roofs, but as Akbari/Rosenfeld
indicates, residential roofs are sloped. In NC and throughout most of the
country, home roofs tend to be slate gray or black, red or some other dark
color. Since homeowners don't want white roofs (or white cars either) due
to the fact that when they get dirty it is much more noticeable, roofs made
of darker materials that reflect more light in the near (solar) IR are
proposed for them.
I once tried an experiment where I completely covered my car in aluminum
foil (no pictures available, unfortunately) to see the effect on inside
temperature. It did make a difference of around 10-15 degrees F. White
painted metal on the roof or hood of a car is quite a bit cooler than darker
colors, though, at least 10-15degrees F. White car advocates should note
that a great deal of the heating in the passenger compartment is through the
windshield and windows and depends on the sun angle, so white paint alone
won't solve the problem.
Cars are a lot like little houses, with windows, roofs and doors. The foam
material in the roof known as the headliner or roof liner is analogous to
the insulation in the attic of a home. If it can be shown that significant
reductions in GHG emissions are possible by reducing the heat gain inside a
vehicle, the type headliner material may be as important or more so than the
exterior paint color. Those expandable Al windshield sun shades also help
and keep the interior from getting as hot as it would otherwise, requiring
less AC to cool the car on startup.
1. 7:45 am, overcast, ambient sun temperature 71F
a. white 70F
b. white 70F
c. black 73F
d. dark blue 73F
e. dark blue 74F
f. dark green 74F
2. 9:10 am, partly sunny, ambient sun temp. 77F
a. white 87F
b. white 83F
c. black 98F (same as in 1, but in partial shade)
d. black 110F (not in shade)
e. dark blue 118F
f. dark green 116F
3. 12:10pm, sunny, ambient sun temp. 81F
a. white 107F
b. white 109F
c. black 145F
d. black 145F
e. dark blue 143F
f. dark blue 143F
g. dark green 146F
4. ranges:
white 70-108F
black 73-145F
dark blue 73-144
dark green 74-146
So the white car roof temperature was about 37F lower than the black, dark
blue or dark green, quite a bit more than my estimate. But, since we don't
travel on top of the car, these numbers are less informative than if they
were correlated with internal measurements.
One interesting side note is the potential for offsetting CO2eq forcing from
making all surface passenger vehicles in the world white. Assuming one
billion vehicles (cars, busses and trucks), an average reflectable surface
area of 50SF per vehicle, and a starting albedo of 0.2 going to 0.8, the
estimated area would be around 1800 square miles or about enough to offset
7% of the global GHG forcing expected to be added in 2009 (pre-recession
estimate). These are very fuzzy numbers as most of the vehicles are out of
the tropics and wouldn't receive as much sunlight as in the case of a
tropical desert with generally clear skies. And of course, like with the
roofs and pavement, the offset only occurs as long as the surface exists
with that level of reflectivity, while the CO2eq forcing will be around much
longer, from decades to centuries. So, should EPA include tax credits for
purchases of white vehicles along with all the other tax incentives to
encourage the CO2eq offset as well as lowered emissions from reduced A/C?
And as for the clunker program, a clunker is a clunker, but should they and
new cars also have color ratings?