Some random jottings ....
Many large trailers at one time used LR wheels as they matched the
wheels on farmers' LRs.
Your existing tyres are intended for a 16" rim. I'm not aware of LR
using anything other than 16" rims for Defender and earlier, RRC and
Disco 1.
Your 195/75R16C tyre has a higher load index (107/105) than a
205(/80)R16 which is usually 99 or 104 for the reinforced ones. The 104
rating seems most common these days.
If the wheels have the larger holes for the larger valve body of the
existing tubes you need to be looking at older rims to get that large
hole. You can get a spacer ring to use small diameter valve bodies
(common today) into large hole rims. It doesn't work the other way!
6 3/8" across the rim flanges suggests that it's a 5.5" rim. This was
the common rim for 7.50x16 tyres on LR 88 and 109, 90 and 110. Most, if
not too recent, are likely to have the large valve body hole. They
were very common.
Keep your existing tyres if OK. I'm pretty certain that they'll fit the
5.5" rim fine if they are OK on your existing rim. The 6.0" rim from the
later Defender may not suit your existing tyre so well.
3 7/8" between stud centres (not the usual way of measuring this
feature, but the easiest) matches the afore-mentioned LR models with
9/16" BSF or M16 studs. Re-check this figure - I suspect that yours are
not 4". You didn't mention your stud size but I feel sure that you'll
match this also.
The hub support hole on these LR rims is about 4 1/2".
Your rim offset works out at around 1 7/16" (36.5mm). The 5.5" rim used
by LR had several offsets during its life. They were about this
dimension initially reducing to 33mm on Defender.
I'm pretty sure that you've got LR 5.5" rims. Any standard LR wheel with
7.50x16 tyres should have them. Choose one with the large valve hole if
you want to re-use your existing tubes.
If you're really pushed to get this moved and struggle to find these
rims, Disco 1 rims may be more easily obtained. They are 6.0", though,
and look different. See comment above.
If you tell us where you are located someone may have some/know someone
who has.