FYI NiCad write up:
I know most will balk at the energy desity, and I by and large agree.
However, if you want a CHEAPER, rugged, high life cycle (1000-1500)
mid-range pack (<10Ahr), then it may work. For a small hub project,
say for a fun beater bike, paying $250 vs, $125 for lead-acid, would
be worth it in weight, and life cycle.
SOURCE: BAttery University
The nickel-cadmium battery
Swedish Waldmar Jungner invented the nickel-cadmium battery in 1899.
At that time, the materials were expensive compared to other battery
types available and its use was limited to special applications. In
1932, the active materials were deposited inside a porous nickel-
plated electrode and in 1947 research began on a sealed nickel-cadmium
battery.
Rather than venting, the internal gases generated during charge were
recombined. These advances led to the modern sealed nickel-cadmium
battery, which is in use today.
Nickel-cadmium prefers fast charge to slow charge and pulse charge to
DC charge. It is a strong and silent worker; hard labor poses little
problem. In fact, nickel-cadmium is the only battery type that
performs well under rigorous working conditions. All other chemistries
prefer a shallow discharge and moderate load currents.
Nickel-cadmium does not like to be pampered by sitting in chargers for
days and being used only occasionally for brief periods. A periodic
full discharge is so important that, if omitted, large crystals will
form on the cell plates (also referred to as memory) and the nickel-
cadmium will gradually lose its performance.
Among rechargeable batteries, nickel-cadmium remains a popular choice
for two-way radios, emergency medical equipment and power tools. There
is shift towards batteries with higher energy densities and less toxic
metals but alternative chemistries cannot always match the superior
durability and low cost of nickel-cadmium.
Here is a summary of the advantages and limitations of nickel-cadmium
batteries.
Advantages
Fast and simple charge, even after prolonged storage.
High number of charge/discharge cycles - if properly maintained,
nickel-cadmium provides over 1000 charge/discharge cycles.
Good load performance - nickel-cadmium allows recharging at low
temperatures.
Long shelf life - five-year storage is possible. Some priming prior to
use will be required.
Simple storage and transportation - most airfreight companies accept
nickel-cadmium without special conditions.
Good low temperature performance.
Forgiving if abused - nickel-cadmium is one of the most rugged
rechargeable batteries.
Economically priced - nickel-cadmium is lowest in terms of cost per
cycle.
Available in a wide range of sizes and performance options - most
nickel-cadmium cells are cylindrical.
Limitations
Relatively low energy density.
Memory effect - nickel-cadmium must periodically be exercised
(discharge/charge) to prevent memory.
Environmentally unfriendly - nickel-cadmium contains toxic metals.
Some countries restrict its use.
Relatively high self-discharge - needs recharging after storage
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